Details
Chinese Manufacturer Supply TRIFLUOROACETALDEHYDE HYDRATE, 75% AQ. SOL. 421-53-4 On Stock with Competitive Price
- Molecular Formula: C2H3 F3 O2
- Molecular Weight: 116.04
- Vapor Pressure: 4740mmHg at 25°C
- Melting Point: 69-70℃
- Refractive Index: 1.33
- Boiling Point: 141.1°Cat760mmHg
- PKA: 10.22±0.41(Predicted)
- Flash Point: 39.2°C
- PSA： 40.46000
- Density: 1.582g/cm3
- LogP: -0.14060
TRIFLUOROACETALDEHYDE HYDRATE, 75% AQ. SOL.(Cas 421-53-4) Usage
|
Safety Profile |
Moderately toxic by ingestion,intravenous, and intraperitoneal routes. When heated todecomposition it emits very toxic fumes of F??. |
InChI:InChI=1/C2HF3O.H2O/c3-2(4,5)1-6;/h1H;1H2
421-53-4 Relevant articles
Catalytic vapor-phase oxidation of 2,2,2-trifluoroethanol
Mimura, Hideyuki,Watanabe, Akio,Kawada, Kosuke
, p. 519 - 523 (2006)
The synthesis of trifluoroacetaldehyde b...
A simple and practical synthesis of α-trifluoromethylated alcohols in water
Loh, Teck-Peng,Li, Xu-Ran
, p. 5611 - 5622 (1999)
A simple and practical preparation of α-...
Direct aldol reaction of trifluoroacetaldehyde ethyl hemiacetal with ketones by use of the combination of amines and acids
Funabiki, Kazumasa,Nagaya, Hideyuki,Ishihara, Mika,Matsui, Masaki
, p. 5049 - 5053 (2006)
Trifluoroacetaldehyde ethyl hemiacetal r...
Ru-Catalyzed Deoxygenative Regioselective C8-H Arylation of Quinoline N-Oxides
Kim, Jinwoo,Kim, Suhyeon,Kim, Dongwook,Chang, Sukbok
supporting information, p. 13150 - 13158 (2019/08/22)
Regioselective C-H functionalization on ...
1,2-Bis(trifluoromethyl)ethene-1,2-dicarbonitrile: (2+2) cycloadditions with vinyl ethers
Urrutia-Desmaison, Gonzalo,Huisgen, Rolf,Noeth, Heinrich
experimental part, p. 1 - 16 (2012/03/07)
The title compound (short version: BTE) ...
Tetrahydropyridinyl and Dihydropyrrolyl Compounds and the Use Thereof
-
Page/Page column 37, (2011/06/24)
The invention relates to tetrahydropyrid...
Magnesium metal-mediated reductive trifluoromethylation of aldehydes with phenyl trifluoromethyl sulfone
Zhao, Yanchuan,Zhu, Jieming,Ni, Chuanfa,Hu, Jinbo
scheme or table, p. 1899 - 1904 (2010/08/19)
An unprecedented reductive nucleophilic ...
421-53-4 Process route
-
-
76-05-1
trifluoroacetic acid
-
-
421-53-4
2,2,2-trifluoro-1,1-ethanediol
| Conditions | Yield |
|---|---|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
at -78 ℃;
|
83%
|
|
With
lithium aluminium tetrahydride; diethyl ether;
|
|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
at -10 - -5 ℃;
for 1.5h;
|
|
|
With
lithium aluminium tetrahydride;
at 20 ℃;
for 15h;
|
-
-
75-46-7
trifluoromethan
-
-
421-53-4
2,2,2-trifluoro-1,1-ethanediol
| Conditions | Yield |
|---|---|
|
With
sodium hydride; sodium methylsulfinylmethanide;
In
dimethyl sulfoxide;
at 70 ℃;
for 0.5h;
|
85%
|
|
With
sulfuric acid; potassium tert-butylate;
In
N,N-dimethyl-formamide;
at -10 - 20 ℃;
for 1h;
|
60%
|
421-53-4 Upstream products
-
421-07-8
1,1,1-trifluoropropane
-
353-85-5
trifluoroacetonitrile
-
76-05-1
trifluoroacetic acid
-
407-25-0
trifluoroacetic anhydride
421-53-4 Downstream products
-
434-39-9
3-nitro-1,1,1-trifluorobutan-2-ol
-
453-35-0
1,1,1-trifluoro-3-nitro-2-propanol
-
86884-21-1
rac-4,4,4-trifluoro-3-hydroxybutanoic acid
-
31185-49-6
2,2,2-Trifluoraethylidoncyclohexylamin
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